Ken,
the density of silver is 10,5 (g/cm³), CuNi alloy is approx 8,9
theoretically a silver ccoin should be heavier than an CuNi version with the same specifications
but for example belgium 500Fr 1980 exists in silver plated version and silver version, both same sizes and weight...
everything depends on the alloy used, so I believe the difference can't be made using a scale
If you can't tell by the colour (get a coin that you know is silver, and one that you know is cupro-nickel and check them out; the silver one will usually look slightly matter and 'whiter'), the other good test I know is the 'ring' test (usually better for larger coins, and over .800 fine):
Balance the coin on the end of a finger and tap it with something hard, but not so hard as to make a mark (I find a pencil or a Bic is usually good). Silver coins will ring very nicely; Cu-Ni won't.
In the old big houses, tea-bells used to be made out of silver for that reason.